\(n_{CuCl_2}=0,1.0,3=0,03mol\)

PTHH: \(CuCl_2+2KOH\rightarrow2KCl+Cu\left(OH\right)_2\)

\(Cu\left(OH\right)_2\rightarrow^{t^o}CuO+H_2O\)

\(m_{CuO}=0,03.80=2,4g\)

a, \(FeCl_3+3NaOH\rightarrow3NaCl+Fe\left(OH\right)_3\)

\(2Fe\left(OH\right)_3\underrightarrow{t^o}Fe_2O_3+3H_2O\)

b, \(n_{FeCl_3}=0,4.2=0,8\left(mol\right)\)

Theo PT: \(n_{NaCl}=3n_{FeCl_3}=2,4\left(mol\right)\)

\(\Rightarrow C_{M_{NaCl}}=\dfrac{2,4}{0,4+0,2}=4\left(M\right)\)

c, \(n_{Fe_2O_3}=\dfrac{1}{2}n_{Fe\left(OH\right)_3}=\dfrac{1}{2}n_{FeCl_3}=0,4\left(mol\right)\)

\(\Rightarrow m_{Fe_2O_3}=0,4.160=64\left(g\right)\)

\(n_{FeCl_3}=0,4.2=0,8\left(mol\right)\)

PTHH:

\(FeCl_3+3NaOH\rightarrow Fe\left(OH\right)_3+3NaCl\)

0,8         2,4                 0,8             2,4

\(2Fe\left(OH\right)_3\underrightarrow{t^o}Fe_2O_3+3H_2O\)

0,8                 0,4         1,2

\(C_{M\left(NaCl\right)}=\dfrac{2,4}{0,6}=4\left(M\right)\)

\(m_{Fe_2O_3}=0,4.160=64\left(g\right)\)

\(n_{FeCl3}=2.0,4=0,8\left(mol\right)\)

PTHH : \(FeCl_3+3NaOH\rightarrow Fe\left(OH\right)_3+3NaCl\)

              0,8----------------------->0,8----------->2,4

b) \(C_{MNaCl}=\dfrac{2,4}{0,4+0,2}=4M\)

c) \(2Fe\left(OH\right)_3\xrightarrow[]{t^o}Fe_2O_3+3H_2O\)

0,8--------------->0,4

\(\Rightarrow a=m_{Fe2O3}=0,4.160=64\left(g\right)\)

nCuSO4= 32/160=0.2 mol

nNaOH= 2*0.25=0.5 mol

2NaOH + CuSO4 --> Na2SO4 + Cu(OH)2

Bđ: 0.5_______0.2

Pư: 0.4_______0.2_______0.2________0.2

Kt: 0.1________0________0.2________0.2

Cu(OH)2 -to-> CuO + H2O

0.2___________0.2

mCuO= 0.2*80=16g

mNaOH ( dư) = 0.1*40=4g

mNa2SO4= 0.2*142=28.4g

\(n_{NaOH}=\dfrac{20}{40}=0,5\left(mol\right)\)

a) \(CuCl_2+2NaOH\rightarrow Cu\left(OH\right)_2+2NaCl\left(1\right)\)

     \(Cu\left(OH\right)_2\xrightarrow[t^o]{}CuO+H_2O\left(2\right)\)

b) \(Pt\left(1\right):n_{Cu\left(OH\right)2}=\dfrac{1}{2}n_{NaOH}=0,25\left(mol\right)\)

  \(Pt\left(2\right):n_{Cu\left(OH\right)2}=n_{CuO}=0,25\left(mol\right)\Rightarrow m_{Cu}=0,25.64=16\left(g\right)\)

c) Pt(1) : \(n_{NaOH}=n_{NaCl}=0,5\left(mol\right)\Rightarrow m_{NaCl}=0,5.58,5=29,25\left(g\right)\)

a)

\(FeSO_4 + 2NaOH \to Fe(OH)_2 + Na_2SO_4\)

b)

\(n_{FeSO_4} = 0,4.0,5 = 0,2(mol) ; n_{NaOH} = 0,5.0,5 = 0,25(mol)\)

Ta thấy : \(2n_{FeSO_4} = 0,4 > n_{NaOH} = 0,25\) nên FeSO₄ dư.

Theo PTHH : 

\(n_{Fe(OH)_2} = 0,5n_{NaOH} = 0,125(mol)\\ \Rightarrow m_{Fe(OH)_2} = 0,125.90 = 11,25(gam)\)

c)

\(4Fe(OH)_2 + O_2 \xrightarrow{t^o} 2Fe_2O_3 + 4H_2O\)

Theo PTHH : 

\(n_{Fe_2O_3} = 0,5n_{Fe(OH)_2} = 0,0625(mol)\\ \Rightarrow m_{Fe_2O_3} = 0,0625.160 = 10(gam)\)

\(n_{CuCl_2}=\dfrac{1,35}{135}=0,01(mol)\\ n_{KOH}=\dfrac{28.10}{100.56}=0,05(mol)\\ a,CuCl_2+2KOH\to Cu(OH)_2\downarrow+2KCl\\ Cu(OH)_2\xrightarrow{t^o}CuO+H_2O\\ \dfrac{n_{CuCl_2}}{1}<\dfrac{n_{KOH}}{2}\Rightarrow KOH\text{ dư}\\ b,n_{CuO}=n_{Cu(OH)_2}=0,01(mol)\\ \Rightarrow m_{CuO}=0,01.80=0,8(g)\)

\(c,n_{KCl}=0,02(mol);n_{KOH(dư)}=0,05-0,01.2=0,03(mol)\\ \Rightarrow m_{Cu(OH)_2}=0,01.98=0,98(g);m_{KCl}=0,02.74,9=1,49(g)\\ \Rightarrow \begin{cases} C\%_{KCl}=\dfrac{1,49}{1,35+28-0,98}.100\%=5,25\%\\ C\%_{KOH(dư)}=\dfrac{0,03.56}{1,35+28-0,98}.100=5,92\% \end{cases}\)